全文获取类型
收费全文 | 13200篇 |
免费 | 2347篇 |
国内免费 | 1204篇 |
专业分类
化学 | 3168篇 |
晶体学 | 206篇 |
力学 | 3506篇 |
综合类 | 160篇 |
数学 | 2347篇 |
物理学 | 7364篇 |
出版年
2024年 | 18篇 |
2023年 | 119篇 |
2022年 | 266篇 |
2021年 | 377篇 |
2020年 | 382篇 |
2019年 | 336篇 |
2018年 | 324篇 |
2017年 | 442篇 |
2016年 | 579篇 |
2015年 | 529篇 |
2014年 | 762篇 |
2013年 | 1239篇 |
2012年 | 838篇 |
2011年 | 1002篇 |
2010年 | 820篇 |
2009年 | 963篇 |
2008年 | 990篇 |
2007年 | 965篇 |
2006年 | 827篇 |
2005年 | 703篇 |
2004年 | 582篇 |
2003年 | 554篇 |
2002年 | 444篇 |
2001年 | 393篇 |
2000年 | 345篇 |
1999年 | 290篇 |
1998年 | 334篇 |
1997年 | 200篇 |
1996年 | 165篇 |
1995年 | 132篇 |
1994年 | 149篇 |
1993年 | 125篇 |
1992年 | 87篇 |
1991年 | 82篇 |
1990年 | 62篇 |
1989年 | 43篇 |
1988年 | 43篇 |
1987年 | 39篇 |
1986年 | 33篇 |
1985年 | 48篇 |
1984年 | 25篇 |
1983年 | 18篇 |
1982年 | 18篇 |
1981年 | 8篇 |
1980年 | 8篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1976年 | 5篇 |
1973年 | 3篇 |
1957年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
61.
《Comptes Rendus Mecanique》2014,342(10-11):595-609
We change a previous time-stepping algorithm for solving a multi-scale Vlasov–Poisson system within a Particle-In-Cell method, in order to perform accurate long-time simulations. As an exponential integrator, the new scheme allows us to use large time steps compared to the size of the oscillations in the solution. 相似文献
62.
《Applied Mathematical Modelling》2014,38(9-10):2505-2521
This paper investigates the essential conditions to improve the accuracy of a resistance spot welding computational study of advanced zinc coated steel sheets using rounded tip electrode. An experimental analysis is performed to highlight the required considerations for a suitable simulation. A sequential Electrical-Thermal-Metallurgical and Mechanical (ETMM) finite element analysis with appropriate precautions of the contact conditions enables to accurately simulate the nugget development during the welding. A critical smooth evolution of the contact radius is required. A fine meshing with an interfacial mesh size of at least 0.05 × 10−3 m combined with a coupling time step of 0.0025 s between the electrical-thermal-metallurgical and the mechanical analysis allows a regular incrementation of the contact radius, without burdening the time computing. Accurate values of the contact resistance depending on the interfacial pressure and temperature are essential for a good simulation of the nugget size. The ETMM calculation is successfully extended to the simulation of the welding of a typical two sheets assembly. 相似文献
63.
《Applied Mathematical Modelling》2014,38(19-20):4796-4803
We consider the computational analysis of processes within the spatially-distributed model simulating the glycolytic reaction taking place in the one-side fed open chemical reactor. The main point of the simulation is the decomposition of the reaction–diffusion system into unidirectional reaction in a bulk supplied by feedback terms stated as boundary conditions on the lower boundary of the reactor, i.e. the unique plane where an exchange with an outer medium is possible within the real experimental situation. Analysis of the curvature of the reagents distribution curves proves kinematic character of the observed lateral waves corresponding to the picture of experimentally observed glycolytic traveling waves. At the same time, their origin relates to diffusion of the reagents in a vertical cross-section of the reactor. Study of the solutions for the concerned reaction–diffusion model in the case of stochastically different diffusion coefficients reveals the Turing structures. 相似文献
64.
The blended-fuel based eddy-dissipation-concept combustion model was newly developed in the FireFOAM framework, and applied to simulate 30 cm×30 cm heptane-ethanol pool fire. Comparison was made of fire height, centerline temperature against experimental measurements, which shows that they match very well with each other. However, further studies are needed to examine the validation of this model in fire simulations with various scales. 相似文献
65.
Dr. Paula Gómez‐Álvarez Prof. Sofia Calero 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(52):18705-18708
The separation of carbon dioxide from flue gas is essential for the reduction of greenhouse gas emissions. In adsorptive methods, the challenge lies in the choice of suitable porous materials. Among all zeolite topologies, a number of adsorbents with pore dimensions in the range of the guest molecules were identified to allow an excellent separation by diffusion, and MRE and AFO zeolite topologies appear to be the best candidates based on equilibrium adsorption. Also, it was found that the behavior of this gas mixture in DFT and APD zeolites differed from the normal behavior. 相似文献
66.
Existing selective pulses are mainly constructed in the forms of classically shaped pulses, such as the Gaussian pulses, or generated by using numerical optimization methods. However, all of these pulses are highly sensitive to radiofrequency (RF) intensity variation, which means their performance is highly dependent on the accuracy and stability of the RF intensity. Even a slight RF intensity deviation can cause severe degradation in the excitation profile. To solve this problem, we propose a method for narrow selective excitation by sequential application of a pair of phase‐opposite asymmetric adiabatic pulses, all within two scans. By retaining the adiabatic character, the new method is highly robust to RF intensity variation. Moreover, it has flexible excitation bandwidth, ranging from line‐selective to narrow‐band‐selective pulses. The method is tested both in numerical simulations and solution‐state NMR experiments. 相似文献
67.
Understanding the Structural Differences between Spherical and Rod‐Shaped Human Insulin Nanoparticles Produced by Supercritical Fluids Precipitation 下载免费PDF全文
Dr. Yeonju Park Yongil Seo Dr. Boknam Chae Prof. Dongjin Pyo Prof. Hoeil Chung Prof. Hyonseok Hwang Prof. Young Mee Jung 《Chemphyschem》2015,16(2):476-482
In this study, the thermal denaturation mechanism and secondary structures of two types of human insulin nanoparticles produced by a process of solution‐enhanced dispersion by supercritical fluids using dimethyl sulfoxide (DMSO) and ethanol (EtOH) solutions of insulin are investigated using spectroscopic approaches and molecular dynamics calculations. First, the temperature‐dependent IR spectra of spherical and rod‐shaped insulin nanoparticles prepared from DMSO and EtOH solution, respectively, are analyzed using principal component analysis (PCA) and 2D correlation spectroscopy to obtain a deeper understanding of the molecular structures and thermal behavior of the two insulin particle shapes. All‐atom molecular dynamics (AAMD) calculations are performed to investigate the influence of the solvent molecules on the production of the insulin nanoparticles and to elucidate the geometric differences between the two types of nanoparticles. The results of the PCA, the 2D correlation spectroscopic analysis, and the AAMD calculations clearly reveal that the thermal denaturation mechanisms and the degrees of hydrogen bonding in the spherical and rod‐shaped insulin nanoparticles are different. The polarity of the solvent might not alter the structure or function of the insulin produced, but the solvent polarity does influence the synthesis of different shapes of insulin nanoparticles. 相似文献
68.
Rocio Bueno‐Perez Dr. Juan J. Gutiérrez‐Sevillano Dr. David Dubbeldam Prof. Patrick J. Merkling Prof. Sofia Calero 《Chemphyschem》2015,16(13):2735-2738
The separation of pentanol isomer mixtures is shown to be very efficient using the nanoporous adsorbent zeolitic imidazolate framework ZIF‐77. Through molecular simulations, we demonstrate that this material achieves a complete separation of linear from monobranched—and these from dibranched—isomers. Remarkably, the adsorption and diffusion behaviors follow the same decreasing trend, produced by the channel size of ZIF‐77 and the guest shape. This separation based on molecular branching applies to alkanes and alcohols and promises to encompass numerous other functional groups. 相似文献
69.
Kamonwad Ngamchuea Dr. Kristina Tschulik Shaltiel Eloul Prof. Dr. Richard G. Compton 《Chemphyschem》2015,16(11):2338-2347
Partially blocked electrodes (PBEs) are important; many applications use non‐conductive nanoparticles (NPs) to introduce new electrode functionalities. As aggregation is a problem in NP immobilization, developing an in situ method to detect aggregation is vital to characterise such modified electrodes. We present chronoamperometry as a method for detection of NP surface aggregation and semi‐quantitative sizing of the formed aggregates, based on the diffusion limited current measured at PBEs as compared with the values calculated numerically for different blocking feature sizes. In contrast to voltammetry, no approximations on electrode kinetics are needed, making chronoamperometry a more general and reliable method. Sizing is shown for two modification methods. Upon drop casting, significant aggregation is observed, while it is minimized in electrophoretic NP deposition. The aggregate sizes determined are in semi‐quantitative agreement with ex situ microscopic analysis of the PBEs. 相似文献
70.
Coupling of CFD Simulations and Population Balance Modeling to Predict Brownian Coagulation in an Emulsion Polymerization Reactor 下载免费PDF全文
In this study a framework consisting of a computational fluid dynamics simulation coupled to a population balance model for the modeling of emulsion polymerizations is proposed. The combined approach is used to understand the impact of changing length and time scales, as well as mixing conditions on the particle size distribution (PSD) of a polymer latex under different conditions. It is shown that the effect of agitation rate can have a profound impact on the distribution of ionic species in the reactor, and thus on the evolution of the PSD.